SDS_2016_Dura_Conditioner_Liquid

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5. 5 of 5 Dura Conditioner Liquid Section 16 - Additional Informati on NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING: HEALTH: 1 Fire: 1 Physical Hazard: 0 ABBREVIATIONS: NA: Not Applicable ND: Not Determined NE: Not Established ppm: parts per million G: Gallon mg: Milligram L: Liter gm: Gram mol: Mole kg: Kilogram μ: Micro mm: Millimeter p Pico Pa: Pascals LC: Lethal Concentration LD: Lethal Dose TC: Toxic Concentration TD: Toxic Dose BOD: Biological Oxygen Demand COD: Chemical Oxygen Demand Lo: Lowest ThOD: Theoretical Oxygen Demand Tlm: Threshold Limit H: Hours M: Months D: Days Y: Years W: Weeks ACGIH: American Conference of Governmental Industrial Hygienist CPR: Controlled Product’s Regulation DSL: Canadian Domest ic Substances List NDSL: Canadian Non - domestic Substance List IARC: International Agency for Research for Cancer NOEL: No Observed Effect Level NOAEL: No Observed Adverse Effect Level OSHA: Occupational Safety and Health Administration PEL: Permissibl e Exposure Limit TLV: Threshold Limit Value THIS MATERIAL SAFETY DATA SHEET IS PREPARED IN COMPLIANCE WITH FEDERAL REGULATIONS (29 CFR 1910.1200), THE COMMONWEALTH OF PENNSYLVANIA REGULATIONS (TITLE 34. CHAPTERS 301 - 323) AND CANADIAN WHMIS REGULATIONS, A NY APPLICABLE STATE AND LOCAL REGULATIONS SHOULD BE CONSULTED. THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR, AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION, WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND M ATERIAL IS FURNISHED ON THE CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE THEREOF. Revised A pril 4, 2016

4. 4 of 5 Dura Conditioner Liquid Section 12 - Ecological Information Continued Triphenyl Phosphate Ecotoxicity - Fish Species Data:>0.3 mg/L LC50 Oncorhynchus mykiss 96 h=0.66 mg/L LC50 Pimephales promelas 96 h =0.78 mg/L LC50 Lepomis marchers 96 h= 0.87 mg/L LC50 Pimephales promelas 96 h = 1.2 mg/L LC50 Oryzias latipes 96 h=290.0 mg/L LC50 Lepomis marchers 96 h Ecotoxicity - Water Flea Data: = 1.0 mg/L EC50 water flea 48 h Ecotoxicity - Freshwater Algae Data: = 2.0 mg/L EC50 freshwat er algae 96 h Persistence and Degradability: Not determined. Section 13 - Disposal Considerations Waste from residues / unused products: Waste must be disposed of in accordance with Federal, State and Local regulations. Where possible recyclin g is preferred to disposal or incineration. Section 14 - Transport Information DOT (U.S.) UN/ID No.: UN3082 Proper Shipping Name: Environmentally hazardous substances, liquid, n.o.s.(Triphenyl Phosphate) U.S. DOT - Hazard Class: 9 Packing group: III Triphenyl Phosphate (1 - 5%) DOT Severe Marine Pollutants: Listed Other shipping information: This material meets the definition of a severe marine pollutant. Applies to containers for shipments in bulk or via water transpo rtation. Do not apply this DOT severe marine pollutant information to any ground mode less than 119 gallons. TDG (Canada), UN/ID No.: UN3082 Proper Shipping Name: Environmentally hazardous substances, liquid, n.o.s.(Triphenyl Phosphate) Cl ass: 9 Packing group: III Section 15 - Regulatory Information U.S. REGULATIONS: Not subject to the provisions of SARA 313 Title III Not subject to TSCA 12(b) Export Notification FDA: 21 CFR 175.105, 176.170, 176.180, 175.300, 175.320, 175.380, 175.390, 177.1210, 181.27 Subject to provisions of these regulations. The final formulator is responsible for complying with any limitations listed in specific sections. STATE REGULATIO NS: This product or its ingredients have been evaluated for New Jersey, Pennsylvania, and California Prop 65 supplier notification requirements. Substances that are subject to notification requirements, if any are listed below. Components State Regulations - NJ; PA; CA Prop65 Triphenyl Phosphate Listed (NJRTK) Listed (PARTK) Canadian WHMIS WHMIS Hazard Class: D2B Toxic Materials. Components WHMIS Ingredient Disclosure Triphenyl Phosphate 1 %

1. 1 of 5 Dura Conditioner Liquid Safety Data Sheet Section 1 - Chemical Product and Company Identification Product Name: Dura Conditioner Liquid Company Identification: Reliance Dental Mfg., LLC. 5805 W. 117 th Place Alsip, IL 60803 For Product Information, call: 708 - 597 - 6694 For Medical Information, call: 800 - 535 - 5053 Section 2 - Hazards Identification EMERGENCY OVERVIEW: Caution : May cause respiratory tract, eye and skin irritation. Color: Colorless Physical state: Liquid Odor: Odorless NFPA 704 Health: 1 Fire: 1 Instability: 0 Potential Health Effects: Principle routes of exposure: Inhalation, ingestion, skin and eye contact. Eye: May cause slight irritation. Skin May cause irritation. Inhalation: May cause irritation of respirat ory tract. Elevated processing temperatures may R elease toxic vapors that are harmful if inhaled. Ingestion: May irritate digestive tract. S Section 3 - Composition, Information on Ingredients Item Chemical Name CAS # WT/WT% 01 2 - Ethylhexyl Diphenyl Phosphate 1241 - 94 - 7 90 - 95% 02 Bis(2 - Ethylhexyl) Phenyl Phosphate 16368 - 97 - 1 5 - 10% 03 Triphenyl Phosphate 115 - 86 - 6 1 - 5% Section 4 - First Aid Measures Eye Contact: Rinse immediately with plenty of water, also under the eyel ids. Get medical attention if irritation develops. Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re - use. Get medical attention if irritation develops. Inhalation: Move to fresh air. IF breathing is difficult, give oxygen. If symptoms persist, call a physician. Ingestion: Drink plenty of water. Do not induce vomiting. Get medical attention if irritation develops.

2. 2 of 5 Dura Conditioner Liquid Section 5 - Fire Fighting Measures FLASH POINT: 223  C, 433  F METHOD: COC SUITABLE EXTINGUISHING MEDIA: Use dry chemical, CO2, water spray or “alcohol” foam. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides. Oxides of phosphorus. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: As in any fire, wear self - contained breathing apparatus (pressure - demand, NIOSH approved or equivalent) and full protective gear. UNUSUAL HAZARDS: None known. Section 6 - Accidental Release Measures Personal Precautions: Evacuate area of all unnecessary personnel. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Environmental Precautions: Prevent further leakage or sp illage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up: Soak up with inert absorbent mater (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labeled containers. Dispose of promptly. Clean contaminated surface thoroughly. E Section 7 - Handling and Storage Handling: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Storage: Keep container tightly closed in a dr y and well - ventilated place. Section 8 - Exposure Controls, Personal Protection Components OSHA ACGIH 01 2 - Ethylhexyl Diphenyl Phosphate Not Established Not Established 02 Bis(2 - Ethylhexyl) Phenyl Phosphate Not Established Not Established 03 Tri phenyl Phosphate 3 mg/m3 TWA 3 mg/m3 TWA Engineering measures: Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are proximal to the work - station location. Eye Protection: Sa fety glasses with side - shields. Skin and Body Protection: Lightweight protective clothing. Wear chemically protective gloves, lav coat or apron to prevent prolonged or repeated skin contact. Hand Protection: Impervious gloves. Respiratory Proctection: Use NIOSH approved respirator when ventilation is inadequate. Hygiene Measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks and at the end of workday.

3. 3 of 5 Dura Conditioner Liquid Section 9 - Physical and Chemical Properties Col or: Colorless Odor: Odorless Physical State: Liquid pH: No Data Available Molecular Weight: No Data Available BOILING POINT: 239.0 @ 13hPa; 375  C @ 1.013 hPa Melting Point/Range: No D ata Available Specific Gravity (H 2 O=1): 1.089 Vapor Pressure: 0.26 hPa @ 150  C Evaporation Rate (H 2 O=1): < 1.00 Water Solubility (mg/l): 0.31 Partition Coefficient: 5.3x10 exp5 VOC Content (%): 2.50 % Viscosity (cP): 16.4 mPa.s @ 25  C Refractive Index: 1.508 - 1.512 @ 20  C Section 10 - Stability and Reactivity Stability: Stable at normal conditions. Polymerization: Will not occur. Hazardous Decomposition products: None under normal use. Materials to Avoid: None Known. Conditions to avoid: None known. Section 11 - Toxicological Information Acute Toxicity: Carcinogenic Effects: Not listed by IARC, NT or OSHA as a carcinogen. Component Information: Component information, if any, is listed below 2 - Ethylhexyl Diphenyl Phosphate LD50s and LC50s: Oral LD50 Rat: > 15800 mg/kg: Dermal LD50 Rabbit:>7940 mg/kg Bis(2 - Ethylhexyl) Phenyl Phosphate LD50s and LC50s: Oral LD50 Mouse: 9333 mg/kg Triphenyl Phosphate LD50s and LC50s: Oral LD50 Rat: 3500 mg/kg: Dermal LD50 Rabbit:>7900 mg/kg Section 12 - Ecological Information AQUATIC TOXICITY: Information given is based on data on the components and the ecotoxicology of similar products. 2 - Ethylhexyl Diphenyl Phosphate Ecotoxici ty - Fish Species Data:>0.38 mg/L LC50 Lepomis marchers 96 h>0.38 mg/L LC50 Oncorhynchus mykiss 96 h > 0.38 mg/L LC50 Pimephales promelas 96 hEcotoxicity - Water Flea Data: = 0.15 mg/L EC50 Daphnia Magna 48 h Ecotoxicity - Freshwater Algae Data: = 0.2 mg/L EC50 Selenastrum capricornutum 72

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