SDS PDF 2017 Duraglaze Liquid

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3. 3 of 8 Duraglaze Liquid distance/protected location. Heat/impurities may increase temperature /build pressure/rupture closed containers, spreading fire, increasing risk of burns/injuries. Use water spray to cool unopened containers. Pressure relief system may plug with solids creating risk of overpressure. Special Fire Fighting Procedures: Use a water spray or fog to reduce or direct vapors, and keep containers cool. Water may not be effective in actually extinguishing a fire involving this product. Do not enter fire area without proper protection. Fight fire from a safe location. Structural firefighters must wear SCBA and full protective equipment. Heat/impurities may cause pressure to build and/or rupture closed containers, spreading fire, increasing risk of burns/injuries. ERG Guide No. 128 Section 6 - Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions: Before cleaning any spill or leak, individuals must wear appropriate Personal protective Equipment that is specified is section 8. Deny entry to all unprotected individuals. Remove any contaminated clothing and wash thoroughly before reuse. Environmental Precautions: Extinguish all ignition sources. Keep spills and cleaning runsoffs out of municipal sewers and open bodies of water. Methods and Material for Containment and Cleaning UP Methods for Containment : Prevent further leakage or spillage if safe to do so. Dike and contain spill with inert material (e.g. sand or earth). Methods for Cleaning Up: Maximize v entilation (open doors and windows) and secure all sources of ignition. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water. Eliminate all ignition sources. Evacuate personnel to safe areas. Ventilate the area. Floor may be slippery, use caution. Soak up with inert absorbent material (paper towel, sand, silica gel, sawdust). Avoid breathing vapor. Wear MSHA/NIOSH approved respirator. Note: Spills on porous surfaces can contamin ate ground water. Normal Disposal. Waste Classification: Methyl Ethyl Ketone (78 - 93 - 3), 40 CFR 261.20 - 24. For discard, this is classified as a hazardous waste with the characteristic of ignitability and toxicity. RCRA #D001. Reportable quantity is 100 lbs. (40 CFR 302) Incinerate liquid and contaminated solids in accordance with local, state and federal regulations. (See 40 CFR 268). For small quantity spills, allow solvent in paper towel to evaporate in w ell ventilated areas or outdoors (preferred). Contaminated Packaging: Empty containers should be taken for local recycling or waste disposal. Section 7 - Handling and Storage Precautions for safe Handling Advice on Safe Handling: Store i n accordance with the National Fire Protection Association’s publications NFPA 30, Flammable and Combustible Liquids Code, 29 CFR1910.106 applies to the handling, storage, and use of flammable and combustible liquids. See section 2 for f urther details (Prevention). Conditions for Safe Storage, Including any Incompatibilities Storage Conditions: Handle containers carefully to prevent damage and spillage. Store container in a cool, dry location, away from direct sunlight, heat, s parks, flame, other light sources, or sources of intense heat. Store in accordance with National Fire Protection Association

8. 8 of 8 Duraglaze Liquid Country Regulation All Components Listed EINECS Yes SARA Hazard categories Yes TSCA Inventory Yes Section 16 - Additional Information Hazardous Material Information System (HMIS) Rating HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 2 PERSONAL PROTECTION B National Fire Protection Association (NFPA) HMIS & NFPA Hazard Rating HEALTH 2 FLAMMABILITY 3 INSTABILITY 2 HMIS & NFPA Hazard Rating * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH B = Gloves and Safety Glasses or Chemical Goggles. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no li ability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Reliance Dental Mfg. Co. be liable for any claims, losses, or damages of any third p arty or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if user has been advised of the possibility of such damages. Revised October 2, 2017

7. 7 of 8 Duraglaze Liquid Section 13 - Disposal Considerations Waste Treatment Methods Disposal of Wastes : Observe all Federal, State and Local regulations when disposing of this substance. Section 14 - Transport Information DOT (Domestic Surface T ansportation) IMO / IMDG (Ocean Transportation) ICAO / IATA UN Number UN1993 UN1993 UN1993 UN Proper Shipping Name Un1993, Flammable Liquids, n.o.s . 3, ll Flammable Liquid, n.o.s. Flammable Liquid, n.o.s. Transport Hazard Class DOT Hazard Class: 3 IMDG: 3 Sub Class: Not A pplicable Air Class: 3 Packing Group ll ll ll Environmental Hazard Marine Pollutant: No Special precautions for user: No further information. Section 15 - Regulatory Information Regulatory Overview: The regulatory data in Section 15 is not intended to be all - inclusive, only selected reg ulations are represented. Toxic Substance All components of this material are either listed or exempt from listing Control Act (TSCA): on the TSCA Inventory. WHMIS Classification: B2 D2B US EPA Tier II Hazards: Fire: Yes Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): No EPCRA 311/312 Chemicals and RQs (LBS): Butanone (5,000.00) EPCRA 302 Extremely hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 313 Toxic Chemicals: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 – Carcinogens (.0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 – Developmental Toxins (.0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 – Female Repro Toxins (.0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 – Male Repro Toxins (.0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. New Jersey RTK Substances (>1%): Butanone Pennsylvania RTK Substances (>1%): Butanone

2. 2 of 8 Duraglaze Liquid P403+233 Store in a well ventilated place. Keep container tightly closed. P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations. *Component names ma y have been omitted to protect c onfidential business information (CBI) in compliance with OSHA GHS HCS § 1910.1200 Appendix E. Section 3 – Composition / Information on Ingredient This product contains the following substances that present a hazard within the meaning of th relevant State and Federal Hazardous Substances regulations. Ingredient.Chemical Designations Weight % GHS Classification Notes Butanone – CAS No. 0000078 - 93 - 3 70 - 85 Flam. Liquid 2 - H225; Eye Irrit.2 - H319; STOT SE 3:H336 (1) (2) Methyl Methacrylate CAS No. 0000080 - 62 - 6 0.10 - 1.0 Flam. Liquid 2 - H225 STOT SE 3 - H335; Skin Irrit. - H315; Skin Sens. 1 - H317 (1) (2) In accordance with paragraph (i) of § 1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit [3] PBT - substance or vP vB – substance Section 4 - First Aid Measures General Advice: Provide the SDS to medical personnel for treatment Inhalation: Remove victim to fresh air. Seek immediate medical attention. Eye Contact: If product gets in the eyes, flush with lukewarm water for at least 15 minutes. If irritation occurs, contact a physician. Skin Contact: Rinse thoroughly with lukewarm water, followed by a thorough washing of the affected area with soap and water . If irritation, redness or swelling persists, contact a physician immediately. Clothing: Remove contaminated clothing, wash thoroughly before reuse. Ingestion: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or milk. Never give anything by mouth to an unconscious person. Provide an estimate of the time at which the materials was ingested and the amount of the subs tance that was swallowed. Get medical attention immediately. Section 5 - Fire Fighting Measures Suitable Extinguishing Media: Recommended extinguishing media; alcohol resistant foam, CO 2 , powder, water spray. Unsuitable Extinguishing Media: Water spra y or water stream may not be effective. Specific Hazards Arising from the Chemical: Hazardous decomposition: Oxides of carbon. May yield acrylic monomers. Keep away from heat/sparks/open flames/hot surfaces – No smoking. Keep cool. Ground/bond cont ainer and receiving equipment. Use explosion - proof electrical / ventilating/ light / equipment. Use only non - sparking tools. Take precautionary measures against static discharge. Avoid breathing dust / fume/ gas/ mist/ vapors / spray. Protective Equip ment and Precautions for Firefighters: Wear self - contained breathing apparatus for firefighting if necessary. Do not enter fire area without proper protection . Fight fire from a safe

1. 1 of 8 Duraglaze Liquid Safety Data Sheet Section 1 - Chemical Product and Company Identification Product Name: Duraglaze Company Identification: Reliance Dental Mfg., LLC. 5805 W. 117 th Place Alsip, IL 60803 For Product Information, call: 708 - 597 - 6694 For Medical Information, call: 800 - 535 - 5053 Section 2 - Hazards Identification Classification of the substance or mixture Hazard Class – Phy sical, Health, environmental Category Flammable Liquid 2 Eye Irritation 2 Skin sensitizer 1 Specific Target Organ Toxicity - Single Exposure 3 Label Elements - Pictograms, Signal Word, Hazard Statements, Precautionary Statements, & Supplemental Information Signal Word: Danger Hazard Statements Precautionary Statements – Prevention, Response, Disposal H225 Highly flammable liquid and vapor H317 May cause an allergic skin reaction P210 Keep away from heat/sparks/open flames/hot surfaces - No Smoking H319 May cause serious eye irritation P23 5 Keep cool H336 May cause drowsiness and dizziness P240 Ground and bond container and receiving equipment P241 Use explosion - proof electrical/ventilating/light/.../equipment P242 Use only non - sparking tools P243 Take precautionary measures against static discharge P261 Avoid breathing dust/fume/gas/mist/vapors/spray P264 Wash hands and exposed skin thoroughly after handling P271 Use only outdoors or in a well - ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P302+P352 IF ON SKIN - Wash with soap and water P304+P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing; call a POISON CENTER or doctor/physician if you feel unwell. P 305+P351 IF IN EYES: Rinse continuously with water for several +P338 minutes. Remove contact len ses if present and easy to do continue rinsing. P313 Get medical advice / attention . P321 Specific treatment (see information on this label). P333+313 If skin irritation or a rash occurs: Get medical advice / attention. P337+313 If eye irritation persists: Get medical advice / attention. P340 Remove victim to fresh air and keep at rest in a position comfortable or breathing. P363 Wash contaminated clothing before reuse P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction. [Storage]:

4. 4 of 8 Duraglaze Liquid recommendations. Product residue may r emain in empty containers. Incompatible Materials: Strong oxidizers, strong acids and strong bases. Section 8 - Exposure Controls, Personal Protection Exposure Chemical Name ACGIH NIOSH OSHA Butananone 0000078 - 93 - 3 50 ppm TWA; 100 ppm STEL 200 ppm TWA; 590 mg/m3 TWA 3 00 ppm (885 mg/m3) ST 2 00 ppm TWA; 590 mg/m3 TWA Methyl Methacrylate 0000080 - 62 - 6 50 ppm TWA; 100 ppm STEL 100 ppm TWA; 410 mg/m3 TWA 100 ppm TWA; 410 mg/m3 TWA Carcinogen Data Chemical Name OSHA NTP IARC Butananone 0000078 - 93 - 3 Select Carcinogen: No Known: No Suspected: No Group 1: No Group 2a: No Group 3: No Group 4: No Methyl Methacrylate 0000080 - 62 - 6 Select Carcinogen: No Known: No Suspected: No Group 1: No Group 2a: No Group 2b Group 3: Yes Group 4: No Engineering Controls : Provide adequate ventilation. Where reasonable practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain conce ntrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. Personnel Protective Equipment (PPE) Respiratory Protection: A respirator should be worn whenever workplace conditi o ns warrant a respirators use. None required if airborne concentrations are maintained below the exposure limit listed above. If necessary, use only respiratory protection authorized per U.S. OSHA’s requirement in 29 CFR § 1910.134 or other appropriate govening standard. Eye/Face Protection: Wear safety glasses, chemical goggles when splashing is possible, when dealing with this materials. If necessary, refer to U.S. Osha 29 CFR § 1910.133, or other appropriate governing standard. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes. Skin and Body Protection Complete suit protecting agains chemicals, the type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper removal technique (without touching glove’ s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. General Hygiene Condsiderations: H andle in accordan ce with good industrial hygiene and safety practice. Wash thoroughly after handling. An eyewash station and a

5. 5 of 8 Duraglaze Liquid safety shower are recommended. Food, beverages, and tobacco products should not be carried, stored or consumed where this material is in use. Wash hands thoroughly before eating, drinking, or smoking. Section 9 - Physical and Chemical Properties Appearance: Clear , light yellow or colorless Odor: Pungent, sweet odor PH: Not measured Initial boiling point and boiling range: 175.3 F Evaporation Rate: >1.0 (Butyl Acetate=1) Upper/Lower Flammablility or Lower Explosive Limit: 1.8 Explosive Limits: Upper Explosive Limit:11.5 Specific Gravity: 0.9 5 - 1.0 (H2O = 1) Partition Coefficient n - octanol/water (Log Kow) : Not mea sured Decomposition temperature: Not measured % Volatile: >80% Physical State: Liquid Odor Threshold: Not determind Melting Point/ Freezing point: - 122.8 F Flash Point: 24.8 F/ - 4 C (TCC) Flammability (solid,gas): Not applicable Vapor pressure (Pa): 80 mm Hg @20C Vapor Density : >1.0 (Air=1) Solubility in Water: Partially for resin, moderately f or thinner Auto - ignition Temp . : Not Measured Viscosity (cSt): >30 sec (Zahn #1 cup) Other information: No other relevant information. Section 10 - Stability and Reactivity Note: Materials listed as stable may become unstable up on depletion of inhibitors (such as mequinol or hydroquinone), contact the manufacturer for exact levels and instruction on inhibitor maintenance. Chemical stability: Stable under normal circumstances. Possibility of Haz ardous reactions: No data available. Conditions to avoid: Avoid excessive heat, open flames and all ignition sources. Incompatible Materials: Strong oxidiz er s, strong acids and strong bases. Hazardous Decomposition Products: Oxides of Carbon. May yield acrylic monomers. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Section 11 - Toxicological Information Acute toxicity: Exposure to solvent vapor concent5rations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, naus ea, dizziness, fatigue muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non - allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with pos sible reversible damage.

6. 6 of 8 Duraglaze Liquid Ingredient Oral LD50, mg/kg Skin LD 50, mg/kg Inhalation Vapor LC50, mg/L/ 4hr Inhalation Dust/Mist LC50, mg/L/4hr Inhalation Gas LC50, ppm Butanone 78 - 93 - 3 2 .737.00, Rat Category : 5 6,480.00, Rabbit Category: NA 32.00, Mouse Category: NA No Data Available No Data Available Methyl Methacrylate 80 - 62 - 6 5,000.00 Rat Category: 5 5,000.00, Rabbit Category: 5 29.80 , Rat Category: NA No Data Available No Data Available Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product’s ATE (Acute toxicity Estimate). Classification Category Hazard Description Acute Toxicity (Oral) --- Not Applicable Acute Toxicity (Dermal) --- Not Applicable Acute Toxicity (Inhalation) --- Not Applicable Skin Corrosion/irritation --- Not Applicable Serious Eye Damage/Irritation 2 Causes serious eye irritation Respiratory Sensitization --- Not Applicable Skin Sensitization 1 May cause an allergic skin reaction Germ Cell Mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive Toxicity --- Not Applicable STOT – Single Exposure 3 May cause drowsiness or dizziness STOT – Single Exposure --- Not Applicable STOT – repeated exposure --- Not Applicable Aspiration Hazard --- Not Applicable Section 12 - Ecological Information Toxicity: No additional information provided for this product. See Section 3 for Chemical specific data. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 Crustacea, mg/l ErC50 Algae, mg/l Butanone – (78 - 93 - 3) 400.00, Cyprinodon Variegatus 520.00 Daphnia Magna 500.00 (96hr), Skeletonema Costatum Methyl Methacrylate – (80 - 62 - 6) 79.00, Oncorhynchus Mykiss 69.00 Daphnia Magna 170.00 (96 hr), Selenastrum Capricornutum Persistence and Degradability: There is no data available on the preparation itself. Bioaccumulative Potential: Not measured. Mobility in Soil: No data available. Results of PBT & vPvB Assessment: This product contains no PBT/vPvB chemicals. Other adverse effects: No data available.


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